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Urea SCR (Selective Catalytic Reduction) system has high potential of reducing NOx. But such as system durability and safety under deteriorated catalysts conditions have not been well enough clarified because it is new technology for vehicles. In this paper, current NOx emission level of an engine equipped with urea SCR system is discussed and then exhaust emission characteristics were analyzed when the SCR catalyst and/or oxidation catalyst lose their functions. When both SCR and oxidation catalyst were de-activated, not only NOx but also PM increased remarkably, which were much more than the engine-out emissions. Oxidation catalyst downstream of SCR catalyst was effective to suppress such deteriorations.

A homogeneous Charge Compression Ignition Diesel Combustion (HCDC) system has been experimentally studied for it's effect on exhaust purification of diesel engines. In this system, most fuel is injected into the intake manifold to form homogeneous pre-mixture in the combustion chamber beforehand and the pre-mixture is ignited with a small amount of fuel directly injected into the cylinder by a conventional injection system. Because this system performs homogeneous lean-burn, it can realize low emission which cannot be realized by conventional diesel engines without impairing ignition controllability in the operations ranging from idle to full load. In particular, although the operating regions were strictly limited, extremely low Nox emission levels of as low as 10 to 40 ppm were realized with maintaining low smoke emissions, when the ratio of pre-mixed fuel was increased up to approx. 98%.

An experimental and a numerical analysis wereconducted based on the concept of homogeneous charge diesel combustion (HCDC), in which most of the fuel is supplied for pre-mixed homogeneous charge which is compressed in the cylinder and then ignited by small amount of diesel fuel directly injected into a cylinder. At the previous report, It was indicated that simultaneous improvement of NOx and smoke were possible. Especially under a certain condition, NOx was extremely reduced. This report describes the preliminary analysis for the cause of this emission improvement with HCDC method. As result, direct optical observation of the combustion phenomena and numerical analysis using KIVA2 code suggested that low NOx combustion may be caused by lowered combustion temperature and reduced combustion period due to the uniform lean combustion.

Homogeneous Charge Compression Ignition (HCCI) is effective for the simultaneous reduction of soot and NOx emissions in diesel engine. In general, high octane number fuels (gasoline components or gaseous fuels) are used for HCCI operation, because these fuels briefly form lean homogeneous mixture because of long ignition delay and high volatility. However, it is necessary to improve injection systems, when these high octane number fuels are used in diesel engine. In addition, the difficulty of controlling auto-ignition timing must be resolved. On the other hand, HCCI using diesel fuel (diesel HCCI) also needs ignition control, because diesel fuel which has a low octane number causes the early ignition before TDC. The purpose of this study is the ignition and combustion control of diesel HCCI. The effects of parameters (injection timing, injection pressure, internal/external EGR, boost pressure, and variable valve timing (VVT)) on the ignition timing of diesel HCCI were investigated.

The use of biofuel is essential for the reduction of greenhouse gas emission. This study highlights the use of biodiesel as a means of reducing greenhouse gas emission from the diesel engine of heavy-duty vehicles. Biodiesel is fatty acid methyl ester (FAME) obtained through ester exchange reaction by adding methanol to oil, such as rapeseed oil, soybean oil, palm oil, etc. The CO2 emission from combustion of biodiesel is defined to be equivalent to the CO2 volume absorbed by its raw materials or plants in their course of growth. On the other hand, however, operation of diesel engine with biodiesel is known to increase the NOx emission when compared with that with conventional diesel fuel. Then suppressing this NOx increase is regarded as a critical issue. This paper consists of two parts: comprehending the factors of NOx emission increase and improving this emission performance in a diesel engine fuelled with biodiesel.

As a method for reducing exhaust emissions from diesel engines, we have experimented on a homogeneous charge diesel combustion technique (HCDC) whereby a portion of fuel is supplied into the intake port to form a homogeneous premixture, this is then fed into the cylinder from the intake port before ignition of the diesel fuel, which is injected directly into the cylinder. Our results have indicated possibilities of substantially reducing both NOx and smoke emissions. If diesel fuel is premixed with air, the premixture under-goes excessively early self-ignition, making it difficult to maintain ignition timing near top dead center and hence limiting the engine operating conditions. While an important target in emission reduction is to realize stable low-emission combustion during a high-load operation, the actual operation of diesel engines mostly involves partial-load conditions.

Widespread use of biofuels for automobiles would greatly reduce CO2 emissions and increase resource recycling, contributing to global environmental conservation. In fact, activities for expanding the production and utilization of biofuels are already proceeding throughout the world. For diesel vehicles, generally, fatty acid methyl ester (FAME) made from vegetable oils is used as a biodiesel. In recent years, hydrotreated vegetable oil (HVO) has also become increasingly popular. In addition, biomass to liquid (BTL) fuel, which can be made from any kinds of biomass by gasification and Fischer-Tropsch process, is expected to be commercialized in the future. On the other hand, emission regulations in each country have been tightened year by year. In accordance with this, diesel engines have complied with the regulations with advanced technologies such as common-rail fuel injection system, high pressure turbocharger, EGR and aftertreatment system.

Urea SCR (Selective Catalytic Reduction) exhaust after-treatment systems are one of the most promising measures to reduce NOx emissions from diesel engines. Both Cu-zeolite (Cu-SCR) and Fe-zeolite (Fe-SCR) urea SCR systems have been studied extensively but not many detailed studies have been conducted on the combination of both systems. Thus, we carried out studies on such Combined-SCR systems and their capability to reduce NOx under various engine operating conditions. We also conducted transient engine tests using different catalyst systems to compare their performance. The results show that combined-SCR systems can reduce NOx more effectively than Fe-SCR or Cu-SCR alone. The best NOx reduction performance was achieved at a Cu ratio of 0.667 (i.e. Fe: Cu =1: 2). Combined-SCR thus apparently benefits from the characteristics of both Cu-SCR and Fe-SCR, allowing it to reduce NOx over a wide range of operating conditions.